Facile synthesis and characterization of new photochromic trans-dithienylethenes functionalized with pyridines and fluorenes.

نویسندگان

  • Qianfu Luo
  • Yi Liu
  • Xin Li
  • He Tian
چکیده

Three symmetrical and unsymmetrical trans-dithienylethenes functionalized with pyridines and fluorenes have been synthesized by a facile one-pot procedure, and their characteristics and photochromism were investigated. Their fluorescent intensity was efficiently regulated by a photochromic switch using alternative irradiation with UV light and visible light. Moreover, by protonation and complexation, the pyridyl-substituted compounds also showed excellent photoswitching properties with distinguishable color changes. These characteristics are expected to be applicable to potential multi-addressable photoswitch and erasable optical data processing technologies.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

4-Aryl-2, 6-di(pyren-1-yl)pyridines: A facile procedure for synthesis and studying of fluorescence properties

Pyrene and its derivatives exhibit thermal stability, high extinction coefficients, excimer formation, high photoluminescence, long fluorescence lifetime, fluorophoric properties and enhanced charge carrier mobility which make them find applications in optoelectronic area and are useful as large planar synthetic building blocks in supramolecular chemistry. One of the approaches to overcome this...

متن کامل

One-pot Synthesis and Characterization of Highly Functionalized Thiazoles

A facile and efficient one-pot three-step process for the synthesis of 5-acetyl-2-imino-4-methylthiazoles via the cyclocondensation of 3-thiocyanatoacetylacetone with various hydrazine or hydrazide derivatives in EtOH has been developed. 3-Thiocyanatoacetylacetone itself has been synthesized as the intermediate from substitution reaction of thiocyanate with 3-chloroacetylacetone. B...

متن کامل

Microwave-Assisted Three Component Cyclocondensation Reaction: A Facile Synthesis of Highly Functionalized Cyclohexene Derivatives

Microwave-assisted three component cyclocondensation reactions of aldehydes, amides and dienophiles in the presence of acetic anhydride and para-toluenesulfonic acid as a catalyst to afford the highly substituted cyclohexene derivatives, in relatively good yields after several minutes are reported.

متن کامل

Phosphotungstic acid supported on functionalized graphene oxide nanosheets (GO-SiC3-NH3-H2PW): Preparation, characterization, and first catalytic application in the synthesis of amidoalkyl naphthols

Grafting of 3-aminopropyltriethoxysilane (APTS) on graphene oxide (GO) nanosheets followed by reaction with phosphotungstic acid (H3PW12O40, denoted as H3PW) gave a new functionalized GO which was characterized using FT-IR, FESEM, EDX, EDX elemental mapping and ICP-OES techniques. The catalytic activity of this nanomaterial containing phosphotungstic counter-anion H2PW12O40¯ (H2PW) which was de...

متن کامل

Synthesis, Characterization, Luminescent Properties, And Crystal Structure Determination Of a New Platinium (IV) Complexe : trans-[Pt(4-mpy)2Cl4]

The new trans-[Pt(4-mpy)2Cl4] (1) complex (4-mpy is 4-methylpyridine) was prepared from the reaction of H2PtCl6.6H2O with 4-methylpyridine in methanol. Synthesized complex was thoroughly characterized by elemental analysis, IR and 1H-NMR spectroscopy.Elemental analysis data (C, H, N) support the general composition of the title complex and the structure have been established by single-crystal X...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology

دوره 9 2  شماره 

صفحات  -

تاریخ انتشار 2010